مرتضی اصغری

آزمایشگاه پژوهشی فرآیندهای جداسازی (SPRG) دانشگاه کاشان

[ 1 ] - بررسی وبهینه سازی حذف آلاینده کشاورزی پارکوات(گراماکسون) با استفاده از نانوفتوکاتالیست بهبود یافتهTiO2/La,S

افزایش روزافزون پساب‌های کشاورزی به‌خصوص آفت‌کش‌ها در روان آب‌ها، آب‌های سطحی و زیر سطحی و ایجاد خطرات زیست‌محیطی ناشی از این آلاینده‌ها سبب گردیده است که حذف آن‌ها از پساب‌های صنعتی، شهری و روستایی از اهمیت ویژه‌ای برخوردار گردد. وجود آفت‌کش‌ها در پساب‌ها و مخاطرات زیست‌محیطی ناشی از آن، نگرانی‌های عمیقی را درباره سلامت عمومی ایجاد کرده است. پاراکوات (از جمله پرمصرف‌ترین علف‌کش‌ها در ایران و ج...

[ 2 ] - Synthesis and characterization of supported Phenolic resin/Carbon nanotubes Carbon membranes for gas separation

In this work, separation performance of supported carbon membranes produced from Novolac Phenolic resin as the main precursor and carbon nanotubes as nanofiller were investigated for separation of CO2 from N2 and CH4. Supports were produced by carbonization of Novolac Phenolic resin-activated carbon mixture, and selective layer was coated by dip coating of prepa...

[ 3 ] - Effect of nano Zinc Oxide on gas permeation through mixed matrix poly (Amide-6-b-Ethylene Oxide)-based membranes

Poly (amide-6-b-ethylene oxide)/Zinc Oxide (PEBA/ZnO) mixed matrix membranes were fabricated using ethanol/water as solvent by solvent casting method. The concentration of ZnO in membrane was set to 0.1 wt.% and the synthesized membranes were characterized by AFM and FTIR. Effects of ZnO nanoparticle on CO2, CH4 and N2 permeabilities, and CO2/N2<...

[ 4 ] - Effect of nanozeolite 13X on thermal and mechanical properties of Polyurethane nanocomposite thin films

Polyurethane/zeolite 13X nanocomposite films were fabricated using solution casting method. The synthesized nanocomposite films were structurally characterized using SEM, TGA and tensile analysis. SEM images showed appropriate distribution of nanocrystalline zeolite particles within polyurethane matrix. Better thermal stability of nanocomposite films in comparison to neat polyurethane was shown...

[ 5 ] - Synthesis and characterization of novel nanocomposite Chitosan membranes for Ethanol dehydration

Polyacrylonitril (PAN)-supported chitosan (CS) nanocomposite membranes were prepared by cross-linking the CS with 3-aminopropyl-triethoxysilane (APTEOS) via sol-gel method. Pervaporative performances of the CS-SiO2/PAN membrane for dehydration of aqueous alcohol solutions were investigated. From SEM cross-sectional images of the membrane, the spongy pores and the finger-like pores we...

[ 6 ] - A visible light driven doped TiO2 nanophotocatalyst: Preparation and characterization

A useful nanophotocatalyst (La,S-TiO2) was prepared by a sol-gel method and characterized by UV–vis diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), photoluminescence emission spectroscopy (PL) and scanning electron microscopy (FESEM). The results showed that the La,S-TiO2, which calcined at 550 °C, contained only anatase phaseand its crystal size was 23 nm...

[ 7 ] - Nano composite PEBAX® membranes: Effect of zeolite X filler on CO2 permeation

A PEBAX-nano zeolite X mixed matrix membrane was fabricated and operationally characterized using single gas (CO2) permeation. X-ray diffraction (XRD) analysis was used to study the arrangement of polymer chains of mixed matrix membrane. The membranes were characterized by scanning electron microscopy (SEM) to study cross-sectional morphology. The single gas permeability were carried...

[ 8 ] - Synthesis and characterization of nanocrystalline CoAPO-5: Structural and morphological analysis by alteration on hydrothermal parameters

Nano-zeolite CoAPO-5 as a member of AFI family, was synthesized via a hydrothermal treatment, and structurally characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersive X-ray analysis (EDAX). The effects of crystallization temperature and time on the structure of these powder products were studied. XRD patterns of the synthesized powders revealed a h...

[ 9 ] - Nano-sized AlPO4-5 Crystals: Synthesis and characterization

Molecular sieves and zeolites are materials whose crystalline frameworks form nanometer or subnanometer pores. A variety of different crystal structures are known having a range of pore sizes. Because the pore sizes are usually smaller than 2 nm, they are classified as microporous materials. Synthesis of microporous materials is usually conducted by the high temperature treatment (80-200 °C) of...

[ 10 ] - شبیه‌سازی عددی و مطالعه نظری تأثیر پارامترهای عملیاتی در تقطیر غشایی در خلأ

خلیج فارس و مناطق ساحلی آن بزرگترین منبع نفت خام در جهان محسوب می‌شوند. از طرفی، گرمای هدر رفته از صنایع پالایش و پتروشیمی که در محدوده اطراف خلیج‌فارس قرار گرفته‌اند، می‌تواند براساس شرایط ساده خوراک ورودی در تقطیر غشایی، مورد استفاده قرار بگیرد. از این رو، به منظور بهبود عملکرد این سیستم در نمک‌زدایی از آب خلیج فارس و افزایش شار خروجی، مدل انتقال جرم و حرارت به طور همزمان در یک سیستم تقطیر غش...

[ 11 ] - Synthesis and characterization of supported Phenolic resin/Carbon nanotubes Carbon membranes for gas separation

In this work, separation performance of supported carbon membranes produced from Novolac Phenolic resin as the main precursor and carbon nanotubes as nanofiller were investigated for separation of CO2 from N2 and CH4. Supports were produced by carbonization of Novolac Phenolic resin-activated carbon mixture, and selective layer was coated by dip coating of prepa...

[ 12 ] - Effect of nano Zinc Oxide on gas permeation through mixed matrix poly (Amide-6-b-Ethylene Oxide)-based membranes

Poly (amide-6-b-ethylene oxide)/Zinc Oxide (PEBA/ZnO) mixed matrix membranes were fabricated using ethanol/water as solvent by solvent casting method. The concentration of ZnO in membrane was set to 0.1 wt.% and the synthesized membranes were characterized by AFM and FTIR. Effects of ZnO nanoparticle on CO2, CH4 and N2 permeabilities, and CO2/N2<...

[ 13 ] - Effect of nanozeolite 13X on thermal and mechanical properties of Polyurethane nanocomposite thin films

Polyurethane/zeolite 13X nanocomposite films were fabricated using solution casting method. The synthesized nanocomposite films were structurally characterized using SEM, TGA and tensile analysis. SEM images showed appropriate distribution of nanocrystalline zeolite particles within polyurethane matrix. Better thermal stability of nanocomposite films in comparison to neat polyurethane was shown...

[ 14 ] - Synthesis and characterization of novel nanocomposite Chitosan membranes for Ethanol dehydration

Polyacrylonitril (PAN)-supported chitosan (CS) nanocomposite membranes were prepared by cross-linking the CS with 3-aminopropyl-triethoxysilane (APTEOS) via sol-gel method. Pervaporative performances of the CS-SiO2/PAN membrane for dehydration of aqueous alcohol solutions were investigated. From SEM cross-sectional images of the membrane, the spongy pores and the finger-like pores we...

[ 15 ] - A visible light driven doped TiO2 nanophotocatalyst: Preparation and characterization

A useful nanophotocatalyst (La,S-TiO2) was prepared by a sol-gel method and characterized by UV–vis diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), photoluminescence emission spectroscopy (PL) and scanning electron microscopy (FESEM). The results showed that the La,S-TiO2, which calcined at 550 °C, contained only anatase phaseand its crystal size was 23 nm...

[ 16 ] - Nano composite PEBAX® membranes: Effect of zeolite X filler on CO2 permeation

A PEBAX-nano zeolite X mixed matrix membrane was fabricated and operationally characterized using single gas (CO2) permeation. X-ray diffraction (XRD) analysis was used to study the arrangement of polymer chains of mixed matrix membrane. The membranes were characterized by scanning electron microscopy (SEM) to study cross-sectional morphology. The single gas permeability were carried...

[ 17 ] - Synthesis and characterization of nanocrystalline CoAPO-5: Structural and morphological analysis by alteration on hydrothermal parameters

Nano-zeolite CoAPO-5 as a member of AFI family, was synthesized via a hydrothermal treatment, and structurally characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersive X-ray analysis (EDAX). The effects of crystallization temperature and time on the structure of these powder products were studied. XRD patterns of the synthesized powders revealed a h...

[ 18 ] - Nano-sized AlPO4-5 Crystals: Synthesis and characterization

Molecular sieves and zeolites are materials whose crystalline frameworks form nanometer or subnanometer pores. A variety of different crystal structures are known having a range of pore sizes. Because the pore sizes are usually smaller than 2 nm, they are classified as microporous materials. Synthesis of microporous materials is usually conducted by the high temperature treatment (80-200 °C) of...