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full textThe calculation of TV , VT , VV , VV 0 ± rate coe cients for the collisions of the main atmospheric components
The ®rst-order perturbation approximation is applied to calculate the rate coecients of vibrational energy transfer in collisions involving vibrationally excited molecules in the absence of non-adiabatic transitions. The factors of molecular attraction, oscillator frequency change, anharmonicity, 3-dimensionality and quasiclassical motion have been taken into account in the approximation. The ...
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Journal title
volume 12 issue 2
pages 313- 338
publication date 2020-12
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