Tautomeric behaviors of 5-arylazobarbituric acids in different concentrations

Authors

  • Jabbar Khalafy Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran
  • Karim Akbari Dilmaghani, Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran
  • Mina Mohammadzadeh Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran
  • Saeed Rastgar, Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran
  • Zahra Malekpoor, Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran
Abstract:

The NMR spectra of azo dyes, 5-arylazobarbituric (5a-g), 5-arylazo-1,3-dimethylbarbituric(6a-g) and 5-arylazothiobarbituric acids (7a-g) were studied in DMSO-d6 in differentconcentrations. An intramolecular hydrogen bond was observed and indicating that thehydrazone forms is mostly predominant. The peak of the hydrazone proton was severelybroadened and its chemical shift appeared at down field due to intramolecular hydrogen bond.Existence of nitro group at ortho-position on phenyl ring caused the chemical shift value of theproton of hydrazone form in 5a-7a to be more deshielded than other hydrazone protons in 5bg−7b-g due to bifurcated intramolecular hydrogen bond and anisotropic ring-current effect. Dyes6 shows two tautomers in NMR time scale at low concentration in DMSO-d6.

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Journal title

volume 2  issue 2

pages  133- 144

publication date 2009-07-20

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