Synthesis and Properties of Plasticized Sulfur-Montmorillonite Nanocomposites by Melt-Blending

Authors

  • Fateme Zarei Iranian Institute of Research & Development in Chemical Industries (IRDCI), Iranian Academic Center for Education, Culture & Research ( ACECR), Karaj, I.R. IRAN
  • Mohammad Sadegh Hajitarverdi Iranian Institute of Research & Development in Chemical Industries (IRDCI), Iranian Academic Center for Education, Culture & Research ( ACECR), Karaj, I.R. IRAN
  • Mostafa Yazdimamaghani Yazdimamaghani Iranian Institute of Research & Development in Chemical Industries (IRDCI), Iranian Academic Center for Education, Culture & Research ( ACECR), Karaj, I.R. IRAN
  • Narmin Bahrami Adeh Iranian Institute of Research & Development in Chemical Industries (IRDCI), Iranian Academic Center for Education, Culture & Research ( ACECR), Karaj, I.R. IRAN
Abstract:

Plasticized sulfur/montmorillonite nanocomposites were prepared by the melt-blending method and the dispersion of montmorillonite (MMT) and the mechanical properties of the nanocomposites were studied. Natural sodium montmorillonite (NaMMT) and organically modified montmorillonite (OMMT) were used as filler. Scanning electron microscope (SEM), X-Ray powder Diffraction (XRD) and Transmission Electron Microscopy (TEM) indicated that OMMT is dispersed effectively in the plasticized sulfur matrix.The effect of varying amounts of natural sodium montmorillonite (NaMMT) and organically modified montmorillonite (OMMT) on the mechanical properties of the prepared nanocomposites were studied. The compressive, tensile, and flexural strengths of the plasticized sulfur nanocomposites containing OMMT compared to that containing NaMMT were, in general, greatly improved.  Best MMT dispersion observed at 1.6 wt. %.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Melt-Processable Syndiotactic Polystyrene/Montmorillonite Nanocomposites

Monoalkyland dialkyl-imidazolium surfactants were used to prepare organically modified montmorillonites with markedly improved thermal stability in comparison with their alkyl-ammonium equivalents (the decomposition temperatures increased by ca. 100 °C). Such an increase in the thermal stability affords the opportunity to form syndiotactic polystyrene (s-PS)/imidazolium-montmorillonite nanocomp...

full text

Synthesis and Properties of Biobased Polyurethane/Montmorillonite Nanocomposites

Polyurethanes (PURs) are very versatile polymeric materials with a wide range of physical and chemical properties. PURs have desirable properties such as high abrasion resistance, tear strength, shock absorption, flexibility and elasticity. Although they have relatively poor thermal stability, this can be improved by using treated clay. Polyurethane/clay nanocomposites have been synthesized fro...

full text

Influence of Micro and Nano Silica on Mechanical Properties of Plasticized Sulfur Composites

In this paper the influence of two different sizes of silica particles (micro-silica and nano-silica) was studied on mechanical properties of sulfur and sulfur composite. To improve the structural properties, sulfur was plasticized using dicyclopentadiene (DCPD) and methyl styrene (MSt). Plasticized sulfur composite was prepared by melt blending of plasticized sulfur and silica particles. T...

full text

GLASS POLYVINYL CHLORIDE/ MONTMORILLONITE NANOCOMPOSITES Transition temperature and mechanical properties

Polyvinyl chloride (PVC)/organic-montmorillonite composites were prepared by melt intercalation. Their structures and properties were investigated with X-ray diffraction (XRD), differential scanning calorimetry (DSC) and mechanical testing. The results showed that PVC chains could be intercalated into the gallery of organically modified montmorillonite to form exfoliated PVC/organic-montmorillo...

full text

Sulfonated Styrene-(ethylene-co-butylene)-styrene/Montmorillonite Clay Nanocomposites: Synthesis, Morphology, and Properties

Sulfonated styrene-(ethylene-butylene)-styrene triblock copolymer (SSEBS) was synthesized by reaction of acetyl sulfate with SEBS. SSESB-clay nanocomposites were then prepared from hydrophilic Na-montmorillonite (MT) and organically (quaternary amine) modified hydrophobic nanoclay (OMT) at very low loading. SEBS did not show improvement in properties with MT-based nanocomposites. On sulfonation...

full text

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 36  issue 6

pages  1- 9

publication date 2017-12-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023