SOLID STATE REDUCTION OF CHROMITE IN HIGH CARBON FERROCHROMIUM-CHROMITE COMPOSITE PELLETS

Authors

  • A. Ataie1,
  • G. R. Khayati,Y. Firozbakht
  • S. Heshmati-Manesh1,
Abstract:

Abstract: In this paper solid state reduction of high carbon ferrochromium-chromite composite pellets in the temperature range of 900-1350°C was investigated. A two stage reduction mechanism is proposed. The first stage is likely to be controlled by the chemical reaction with activation energy of 127.2kJ/mol. In the second stage, solid state diffusion of carbon through the reaction product layer is suggested to be rate controlling. The activation energy of this stage was calculated to be 93.1kJ/mol. The reduction process was found to be favored by high temperatures as well as high vacuum. The results also show that pre-milling of initial mixture has a negative effect on the reduction degree.

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Journal title

volume 5  issue 1

pages  22- 28

publication date 2008-03

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