Nano-Hybrids Based on Surface Modified Reduced Graphene Oxide Nanosheets and Carbon Nanotubes and a Regioregular Polythiophene
Authors
Abstract:
The multi-walled carbon nanotubes (CNTs) and reduced graphene oxide (rGO) nanosheets were functionalized with 2-hydroxymethyl thiophene (CNT-f-COOTh) and 2-thiophene acetic acid (rGO-f-TAA) and grafted with poly(3-dodecylthiophene) (CNT-g-PDDT and rGO-g-PDDT) to manipulate the orientation and patterning of crystallized regioregular poly(3-hexylthiophene) (P3HT). Distinct nano-hybrid structures including double-fibrillar (5.11−5.18 S/cm), shish-kebab (2.19−2.28 S/cm), and stem-leaf (6.96−7.51 S/cm) were developed using modified CNTs and P3HT. The most effective parameter on morphology of donor-acceptor supramolecules was the surface functionalization and grafting. The electrical conductivities of supramolecules based on P3HT and rGO, rGO-f-TAA, and rGO-g-PDDT ranged in 3.81−3.87, 3.91−3.95, and 10.67−10.70 S/cm, respectively. P3HT chains preferred to interact with their thiophene rings with bared rGO and CNT surfaces, resulting in a conventional face-on orientation. In P3HT/rGO-f-TAA and P3HT/CNT-f-COOTh supramolecular nanostructures patterned with P3HT, the orientation of P3HT chains changed from face-on to edge-on, originating from the strong interactions between the hexyl side chains of P3HTs and functional groups. Nano-hybrids based on grafted rGO demonstrated a patched-like morphology composed of flat-on P3HTs with main backbones perpendicular to the substrate. Based on the ultraviolet-visible and photoluminescence analyses, the flat-on orientation was the best for P3HT chains assembled onto CNT and rGO, which was acquired for CNT-g-PDDT and rGO-g-PDDT nano-hybrids.
similar resources
Electrochemical Chiral Recognition of Naproxen Using L-Cysteine/Reduced Graphene Oxide Modified Glassy Carbon Electrode
The electrochemical response of S- and R-naproxen enantiomers was investigated on L-cysteine/reduced graphene oxide modified glassy carbon electrode (L-Cys/RGO/GCE). The production of the reduced graphene oxide and L-cysteine on the surface of the glassy carbon electrode was done by using electrochemical processes. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were us...
full textCarbon black-intercalated reduced graphene oxide electrode with graphene oxide separator for high-performance supercapacitor
We present a general study on a high performance supercapacitor based on intercalated reduced graphene oxide with carbon black nanoparticles. Graphene oxide sheets were synthesized by oxidation and exfoliation of natural graphite and were reduced using hydroiodic acid in the presence of carbon black nanoparticles. Graphene paper was fabricated by one-step procedure via simultaneous reducing and...
full textStudy and Electrochemical Determination of Tyrosine at Graphene Nanosheets Composite Film Modified Glassy Carbon Electrode
A graphene nanosheets (GNS) film coated glassy carbon electrode (GCE) was fabricated for sensitive determination of tyrosine (Tyr). The GNS-based sensor was characterized by scanning electron microscope and electrochemical impedance spectroscopy. The voltammetric techniques were employed to study electro-oxidation of Tyr. The results revealed that the modified electrode showed an electrocatalyt...
full textA nano-sandwich construct built with graphene nanosheets and carbon nanotubes enhances mechanical properties of hydroxyapatite–polyetheretherketone scaffolds
A nano-sandwich construct was built by combining two-dimensional graphene nanosheets (GNSs) and one-dimensional carbon nanotubes (CNTs) to improve the mechanical properties of hydroxyapatite-polyetheretherketone (HAP-PEEK) scaffolds for bone tissue engineering. In this nano-sandwich construct, the long tubular CNTs penetrated the interlayers of graphene and prevented their aggregation, increasi...
full textElectrically and Electrochemically Active Composite Based on Polyester/Reduced Graphene Oxide/Polypyrrole with Remarkable Washing Durability
full text
Comparative study of the Sevoflurane Asorption Capacity on Carbon Media Impregnated with Titanium Oxide Nanoparticles
Introduction: Occupational exposure to sevoflurane as an anesthetic gases in hospitals, dental clinics and veterinary clinics has been reported in various studies. Considering the harmful effects of sevoflurane anesthetic gas on the health of exposed personnel such as reproductive, preterm delivery and fetal abnormalities and increased spontaneous abortion, it is necessary to remove them from t...
full textMy Resources
Journal title
volume 51 issue 1
pages 60- 70
publication date 2018-06-01
By following a journal you will be notified via email when a new issue of this journal is published.
Hosted on Doprax cloud platform doprax.com
copyright © 2015-2023