EFFICIENT PHOSPHOROUS-SULFUR BOND REDUCTION IN BICYCLIC THIAPHOSPHORANES WITH TRI-n-BUTYLTIN HYDRIDE
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Abstract:
High yield photolytic reduction of a series of thiaphosphoranes Z p SR to give Z p H with UV-light-induced tri-n-butyltin hydride through phosphoranyl radical Z p is described. This reaction is inhibited by a-methylstyrene and initiated by a radical initiator such as azobisisobutyronitrile
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efficient phosphorous-sulfur bond reduction in bicyclic thiaphosphoranes with tri-n-butyltin hydride
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Journal title
volume 4 issue 1
pages -
publication date 1993-03-01
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