Consideration of C-H…O interaction in the heterocyclic organic-inorganic hybrid material: tri-prolinium12- phosphomolibdate heteropolyoxometalate

The inorganic–organic hybrid material triethyl­enetetra­mmonium hexa­chlorido­rhodate(III) chloride

SINGLE CRYSTALS OF THE NEW TITLE COMPOUND [SYSTEMATIC NAME: 1,4,7,10-tetra-zoniadecane hexa-chloridorhodate(III) chloride], [H(3)N(CH(2))(2)NH(2)(CH(2))(2)NH(2)(CH(2))(2)NH(3)][RhCl(6)]Cl, were obtained from the corresponding amine and rhodium trichloride in hydro-chloric acid solution by slow crystallization under diffusion-controlled conditions at room temperature. Its solid-state structure i...

Effect of organic modifiers on the thermo-optic characteristics of inorganic–organic hybrid material films

The thermo-optic coefficient (dn/dT) of inorganic–organic hybrid material films prepared by the sol-gel process of organoalkylsilanes is measured using a prism coupler equipped with a hot stage. The effect of the organic modifier on the variation of dn/dT in inorganic–organic hybrid material films has been investigated. The value of dn/dT becomes more negative with increasing molecular weight o...

Organic/inorganic hybrid as anticratering agent in cathodicelectrocoating

An improved aqueous electrocoating composition containing an anticrater additive which is a reaction product of silane component based on glycidoxy propyl tri methoxysilane and poly oxy propylene diamine. Materials were studied by infrared spectroscopy and particle size analyzer. Crater number of electrocoated sample was evaluated by GM9532p standard. The final electrocoat contains anticrater a...

Photochromic organic–inorganic hybrid materialsw

A two-dimensional organic–inorganic hybrid compound, poly[(ethylenediamine)tri-μ-oxido-oxidocopper(II)molybdenum(VI)]

A new organic-inorganic two-dimensional hybrid compound, [CuMoO(4)(C(2)H(8)N(2))], has been hydro-thermally synthesized at 443 K. The unit cell contains layers composed of CuN(2)O(4) octa-hedra and MoO(4) tetra-hedra. Corner-sharing MoO(4) and CuN(2)O(4) polyhedra form CuMoO(4) bimetallic sites that are joined together through O atoms, forming an edge-sharing Cu(2)Mo(2)O(4) chain along the c ax...