COMBUSTION PERFORMANCE OF Ni-COATED AND UNCOATED HIGH ENERGETIC ALUMINUM NANOPARTICLES

Authors

  • A. Farbod
  • H. Shalchian
  • S. A. Sajjadi
Abstract:

High energetic aluminum nanoparticles are mainly used as additive in solid rocket propellants. However, fabrication of these aluminized energetic materials is associated with decreasing the burning rate of propellants due to problems such as oxidation and agglomeration of nanoparticles. In this study, to improve combustion performance of aluminum nanoparticles, coating by metallic Ni shell was studied. Nickel coating of aluminum nanoparticles was performed through electroless deposition (ED) subsequently, morphology and chemical composition of Ni-coated nanoparticles were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD). These studies show that a uniform Ni layer with a thickness of 10nm is coated on the surface of Al nanoparticles. Thermal analysis of uncoated and Ni-coated aluminum nanoparticles was done using differential thermal analysis (DTA) and thermo gravimetric analysis (TGA). The results of thermal analysis indicate that, coating the aluminum particles by Ni, leads to improvement in combustion performance of aluminum nanoparticles through decreasing critical ignition temperature, ignition delay time of the nanoparticles and promoting the ignition by exothermic chemical reactions between Al and Ni

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Cyclic oxidation behavior of uncoated and aluminum-rich nickel aluminide coated Rene-80 superalloy

In this study, aluminide coating was employed to enhance the high-temperature cyclic oxidation of Rene-80 superalloy at 950ºC. The microstructural aspects and phase constituents of samples were  investigated with scanning electron microscopy (SEM) and x-ray diffraction (XRD) techniques. The result of oxidation tests showed that the weight gain in the uncoated sample was considerably higher than...

full text

Energetic and Exergetic Analysis of Internal Combustion Engine Cogeneration System

In this article, the first and second law analysis of diesel engine based cogeneration system was performed. Fuel utilization efficiency, rate of power, and rate of process heat of the plant were determined and various efficiencies based on both energy and exergy methods and the performance assessment parameters are defined for both the system components and the entire cogeneration plant. The o...

full text

High Performance Nanocomposite Cation Exchange Membrane: Effects of Functionalized Silica-Coated Magnetic Nanoparticles

Nanocomposite cation exchange membranes (CEMs) were prepared by adding various amounts of functionalized silica-coated magnetite nanoparticles to the sulfonated polyethersulfone (sPES) polymeric matrix. The particles were synthesized first by the co-precipitation method (M0). Different surface modifications were then carried out on them by grafting three functional groups of mercaptopropyl, pro...

full text

Physical and magnetic properties of highly aluminum doped strontium ferrite nanoparticles prepared by auto-combustion route

Highly Al3þ ion doped nanocrystalline SrFe12 xAlxO19 (0rxr12), were prepared by the auto-combustion method and heat treated in air at 1100 1C for 12 h. The phase identification of the powders performed using x-ray diffraction show presence of high-purity hexaferrite phase and absence of any secondary phases. With Al3þ doping, the lattice parameters decrease due to smaller Al3þ ion replacing Fe3...

full text

Materials characteristics of uncoated/ceramic-coated implant materials.

In this paper, the biocompatibility of dental implant materials is discussed in the context of both the mechanical characteristics of the materials and the type of surface presented to the surrounding tissues. The proper functioning of the implant depends on whether it possesses the strength necessary to withstand loading within the expected range, with other properties such as elongation being...

full text

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 12  issue 1

pages  28- 34

publication date 2015-03

By following a journal you will be notified via email when a new issue of this journal is published.

Keywords

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023