Catalytic Investigation of Aluminum Effects on Benzene Hydrogenation Selectivity over Nickel Supported HMS/HZSM-5 Composites

Hydrogenation of Levulinic Acid over Nickel Catalysts Supported on Aluminum Oxide to Prepare -Valerolactone

Four types of nickel catalysts supported on aluminum oxide (Ni/Al2O3) with different nickel loadings were synthesized using the co-precipitation method and were used for the hydrogenation of levulinic acid (LA) to prepare γ-valerolactone (GVL). The synthesized Ni/Al2O3 catalysts exhibited excellent catalytic activity in dioxane, and the activity of the catalysts was excellent even after being u...

Platinum nanoparticle shape effects on benzene hydrogenation selectivity.

Benzene hydrogenation was investigated in the presence of a surface monolayer consisting of Pt nanoparticles of different shapes (cubic and cuboctahedral) and tetradecyltrimethylammonium bromide (TTAB). Infrared spectroscopy indicated that TTAB binds to the Pt surface through a weak C-H...Pt bond of the alkyl chain. The catalytic selectivity was found to be strongly affected by the nanoparticle...

Nickel Hydrogenation Composite Catalysts Modified by Zirconium in Competitive Benzene Hydrogenation: Effect of Modifiers

A co-impregnation method was applied to the Ni/Zr-HMS/HZSM-5 catalyst (with various amounts of zirconium) during the hydrogenation of benzene. The physicochemical properties of the prepared nickel catalyst were characterized using X - ray diffraction, X - ray fluorescence, Fourier transform infrared spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy, temperature-programmed desor...

Selectivity control over the catalytic hydrogenation of 1,3-butadiene on Pt(111) and Pd(111) surfaces

Catalytic Decarboxylation of Fatty Acids to Aviation Fuels over Nickel Supported on Activated Carbon

Decarboxylation of fatty acids over non-noble metal catalysts without added hydrogen was studied. Ni/C catalysts were prepared and exhibited excellent activity and maintenance for decarboxylation. Thereafter, the effects of nickel loading, catalyst loading, temperature, and carbon number on the decarboxylation of fatty acids were investigated. The results indicate that the products of cracking ...

Effect of Nickel Particle Size on Alumina Supported Nickel Catalysts for p-Nitrophenol Hydrogenation

The catalytic hydrogenation of p-nitrophenol to p-aminophenol was investigated over alumina supported nickel catalysts prepared by impregnation reduction method and mechanical mixing method. The catalysts were characterized by XRD and FESEM. The results show that the nickel particle diameter of alumina supported nickel prepared by impregnation reduction method (denoted as Ni/Al2O3) is slightly ...