Catalytic application of an organosuperbase denderon grafted on mesoporous SBA-15 and related palladium complex in the aerobic oxidation of alcohols

Authors

  • Davood Kordestani Medical biology Research Center, Kermanshah University of Medical Sciences, Kermanshah-Iran
  • Hojat Veisi Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
  • Mona Hamelian Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
  • Sami Sajjadifar Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
Abstract:

An efficient synthetic method for successful synthesis of amine denderon on SBA-15 and related Pd (II) complex has been developed. This modified mesoporous material was characterized by various techniques such as TEM, XRD, atomic absorption spectroscopy, N2 adsorption-desorption, and FT-IR. The catalytic activities of the prepared catalysts were investigated by employing aerobic oxidation of alcohols as model reactions. The yields of the products were in the range from 75% to 92%. The catalyst can be readily recovered and reused at least 5 consecutive cycles without significant leaching and loss its catalytic activity. Organosuperbase, SBA-15, Palladium complex, Oxidation Organosuperbase, SBA-15, Palladium complex, Oxidation

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Journal title

volume 2  issue Issue 1, pp. 1-81

pages  27- 33

publication date 2014-02-01

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