Birefringence Properties and Surface Relief Grating Formation on Methylacrylate Polymers with Photochromic Side Chains

Investigation of the Surface Relief Grating formation on amorphous azobenzene polymer films

Photoinduced Surface Relief Grating Formation for a Single Crystal of 4-Aminoazobenzene

Photoinduced surface relief grating (SRG) formation for a single crystal of 4-aminoazobenzene was investigated. It was found that SRG could be inscribed on the (001) surface of the crystal, which might suggest that the photoinduced SRG formation is a general phenomenon observed for single crystals of azobenzene-based molecules as well as for azobenzene-based amorphous systems. In addition, the ...

Effective grating theory for resonance domain surface-relief diffraction gratings.

An effective grating model, which generalizes effective-medium theory to the case of resonance domain surface-relief gratings, is presented. In addition to the zero order, it takes into account the first diffraction order, which obeys the Bragg condition. Modeling the surface-relief grating as an effective grating with two diffraction orders provides closed-form analytical relationships between...

Effect of chiral 2-ethylhexyl side chains on chiroptical properties of the narrow bandgap conjugated polymers PCPDTBT and PCDTPT

Two narrow bandgap conjugated polymers containing chiral 2-ethylhexyl side chains were synthesized: poly[(4,4-bis(2-ethylhexyl)cyclopenta-[2,1-b:3,4-b0]dithiophene)-2,6-diyl-alt-(2,1,3-benzothiadiazole)4,7-diyl] (PCPDTBT*) and poly[(4,4-bis(2-ethylhexyl)cyclopenta[2,1-b:3,4-b0]dithiophene)-2,6-diyl-alt[1,2,5]-thiadiazolo[3,4-c]pyridine] (PCDTPT*). The presence of a chiral substituent provides a...

Reversible colorimetric ion sensors based on surface initiated polymerization of photochromic polymers.

Spiropyran containing polymer brushes were used as reversible, photoswitchable optical sensors that show selectivity for different metal ions and drastic changes in surface wettability.