catena-Poly[[trimethyltin(IV)]-μ-2,4,6-trichlorobenzoato]
نویسندگان
چکیده
In the title compound, [Sn(CH(3))(3)(C(7)H(2)Cl(3)O(2))](n), the tin(IV) atom exhibits a slightly distorted trigonal-bipyramidal geometry with two O atoms of symmetry-related carboxyl-ate groups in the axial positions and three methyl groups in the equatorial positions. In the crystal structure, the metal atoms are linked by carboxyl-ate bridges into polymeric chains extending along the b axis.
منابع مشابه
catena-Poly[[trimethyltin(IV)]-μ-5-methylthiophene-2-carboxylato-κ2 O:O′]
In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010].
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-quinaldato]
The title compound, [Sn(CH(3))(3)(C(10)H(6)NO(2))](n), forms an extended one-dimensional chain structure. There are two independent Sn(IV) ions, both of which are in slightly distorted trigonal-bipyramidal coordination environments with two symmetry-related O atoms in the axial sites. In each case, the Sn(IV) ion and one of the three equatorial C atoms lie on a crystallographic twofold axis.
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-phenylseleninato-κ2 O:O′]
In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-1,2,3-benzotriazol-1-ido-κ2 N 1:N 3]
In the title coordination polymer, [Sn(CH(3))(3)(C(6)H(4)N(3))](n), the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with the methyl groups in equatorial positions and two N atoms of two symmetry-related benzotriazolide anions in axial positions. The anion bridges adjacent metal atoms, forming zigzag polymeric chains parallel to [011] and [0[Formula: see text]1].
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-2-phenylbutanoato]
In the title polymeric coordination compound, [Sn(CH(3))(3)(C(10)H(11)O(2))](n), the Sn atom has a distorted trigonal-bipyramidal coordination geometry, with two O atoms of two symmetry-related carboxyl-ate ligands in axial positions and three methyl groups in equatorial positions. In the crystal structure, carboxyl-ate bridges link the metal atoms, forming zigzag chains parallel to the b axis.
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