Stochastic Processes and Brownian Motion

نویسنده

  • J. Cao
چکیده

This last point, however, raises a serious question: how well does equilibrium thermodynamics really motivate our understanding of nonequilibrium phenomena? Is it reasonable for an organometallic chemist to analyze a catalytic cycle in terms of rate-law kinetics, or for a biochemist to treat the concentration of a solute in an organelle as a bulk mixture of compounds? Under many circum­ stances, equilibrium thermodynamics suffices, but a growing number of outstanding problems in chemistry – from electron transfer in light-harvesting complexes to the chemical mechanisms behind immune system response– concern processes that are fundamentally out of equilibrium.

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تاریخ انتشار 2013