Synthesis of ‘reactive’ and covalent polymeric multilayer coatings with durable superoleophobic and superoleophilic properties under water† †Electronic supplementary information (ESI) available: Fig. S1–S15 accounting the growth of NC with and without the LbL deposition process, detailed comparisons of the multilayers of BPEI and NC, the change in the underwater oil-wettability with increasing deposition cycles of NC, the change in the optical transparency of the multilayers under water, the underwater oil-wettability of various model oils on post-modified multilayers of NC, bouncing of oil droplets underwater, the change in adhesive interactions with LbL deposition of NC, beading and wetting of oil droplets on post-modified multilayers under water, the effect of heating, freezing, and chemical and physical insults on the oil-wettability of the multilayers under water, LbL coating of various substrates, the guided transfer of oil droplets under water and the cleaning of oil using superoleophilic cotton under water. See DOI: 10.1039/c7sc01055a Click here for additional data file.
نویسندگان
چکیده
Department of Chemistry, Indian Institute o 781039, India. E-mail: [email protected] † Electronic supplementary information the growth of NC with and without t comparisons of the multilayers of BPEI a oil-wettability with increasing deposition transparency of the multilayers under w various model oils on post-modied mul underwater, the change in adhesive int beading and wetting of oil droplets on p the effect of heating, freezing, and ch oil-wettability of the multilayers under wa the guided transfer of oil droplets unde superoleophilic cotton under water. See D Cite this: Chem. Sci., 2017, 8, 6092
منابع مشابه
A general and facile chemical avenue for the controlled and extreme regulation of water wettability in air and oil wettability under water† †Electronic supplementary information (ESI) available: A detailed experimental section is included in the ESI section and Fig. S1–S7 show a comparison of the growth of NC and change in the dipping solution which is a BPEI/5Acl mixture, post chemical functionalization of multilayers that are developed in the presence and absence of salt, SEM images of multilayers of NC and polymer, bouncing and rolling of oil/water, effect of chemical modification on liquid wettability, characterization of special adhesive-anti-fouling liquid (oil/water) wettability, and effect of various abrasive tests on the synthesized material. See DOI: 10.1039/c7sc02296d Click here for additional data file.
Materials: Dipentaerythitol penta-acrylate (5Acl), branched polyethyleneimine (BPEI, MW~ 25000), propylamine, hexylamine, octylamine, decylamine, sodium dodecyl sulfate (SDS) and Nile red (Technical grade, Sigma-N3013) were aquired from Sigma Aldrich, Bangalore, India. . n-butylamine was bought from Spectrochem Pvt. Ltd., Mumbai, India. HCl and Dimethyl sulfoxide (DMSO) were obtained from Fisch...
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