“ The near infrared 12 A 2 ’ ’ – X 2 A 1 ’ electronic transition of B 3 in a neon matrix ”
نویسنده
چکیده
The 12A00 2 XA 0 1 electronic transition of the B3 molecule with origin band at 5990 cm 1 has been observed in a 6 K neon matrix. A vibrational progression in the spectrum corresponds to the excitation of the m1ða1Þ vibrational mode in the 1 A 00 2 state with a frequency of 1092 cm . The band system was detected after laser ablation of a boron rod and the origin band also after mass-selected deposition of B 3 anions with subsequent neutralization. 2005 Elsevier B.V. All rights reserved.
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