Analytical methods for arsenic speciation analysis

نویسندگان

  • LJUBINKA V. RAJAKOVIĆ
  • ŽAKLINA N. TODOROVIĆ
  • VLADANA N. RAJAKOVIĆ-OGNJANOVIĆ
  • ANTONIJE E. ONJIA
چکیده

Arsenic exists in the form of various chemical species differing in their physicochemical behaviour, toxicity, bioavailability and biotransformation. The determination of arsenic species is an important issue for environmental, clinical and food chemistry. However, differentiation of these species is a quite complex analytical task. Numerous speciation procedures have been studied that include electrochemical, chromatographic, spectrometric and hyphenated techniques. This review presents the relevant research in the field of arsenic speciation analysis with novel applications and significant advances. Stability of arsenic species and each of the analytical steps (sample collection, storage, preservation, extraction) of the arsenic speciation methods is particularly evaluated. Analytical validation and performance of these methods are also reviewed.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Intercomparison of analytical methods for arsenic speciation in human urine.

An intercomparison exercise was conducted for the quantification of arsenic species in spiked human urine. The primary objective of the exercise was to determine the variance among laboratories in the analysis of arsenic species such as inorganic As (As+3 and As+5), monomethylarsonic acid (MMA), and dimethylarsinic acid (DMA). Laboratories that participated had previous experience with arsenic ...

متن کامل

Arsenic, Antimony, Chromium, and Thallium Speciation in Water and Sediment Samples with the LC-ICP-MS Technique

Chemical speciation is a very important subject in the environmental protection, toxicology, and chemical analytics due to the fact that toxicity, availability, and reactivity of trace elements depend on the chemical forms in which these elements occur. Research on low analyte levels, particularly in complex matrix samples, requires more and more advanced and sophisticated analytical methods an...

متن کامل

Human urine certified reference material for arsenic speciation.

BACKGROUND Chemical speciation analysis is essential for the biological monitoring of inorganic arsenic exposure using urine as indicator medium. There is increasing demand for a certified reference material (CRM) of urine matrix for arsenic speciation. METHODS Urine (10 L) was collected from non-occupationally exposed Japanese males. We prepared 954 bottles of urine, each containing approxim...

متن کامل

Arsenic speciation by hydride generation-Quartz furnace atomic absorption spectrometry. Optimization of analytical parameters and application to environmental samples

Analytical parameters of hydride generation, trapping, gas chromatography and atomic absorption spectrometry detection in a quartz cell furnace (HG/GC/QFAAS) device have been optimized in order to develop an efficient and sensitive method for arsenic compounds speciation. Good performances were obtained with absolute detection limits in the range of 0.1 – 0.5 ng for arsenite, arsenate, monometh...

متن کامل

Analytical Chemistry Division Commission on Microchemical Techniques and Trace Analysis* Working Group on Speciation? Determination of Arsenic Species in Environmental and Biological Samples

Identification and quantitative determination methods of arsenic species in environmental and biological samples are discussed. Isolation followed by molecular spectroscopic determination is necessary for rigorous identification while element-specific detections coupled with separation techniques are the choice for quantitative determination. Analytical figures of merit are given for the method...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2013