Synthesis of ThCr2Si2-type arsenides from Bi flux.
نویسندگان
چکیده
LaCo(2)As(2) can be synthesized as pure crystalline material by annealing a mixture of elements in Bi flux. The reaction, however, is accompanied by the incorporation of a small quantity of Bi into the structure and the formation of vacancies in the Co sublattice, which lead to substantial changes in structural and magnetic properties of the material.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 19 شماره
صفحات -
تاریخ انتشار 2011