One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst.

نویسندگان

  • Paula Rubio-Marqués
  • Juan Carlos Hernández-Garrido
  • Antonio Leyva-Pérez
  • Avelino Corma
چکیده

Cyclohexanone oxime is formed from nitrobenzene with 97% yield in a one-pot reaction catalysed by palladium and gold nanoparticles on carbon. The reaction is carried out under hydrogen at 60 °C and the overall transformation involves a multi-step catalysed mechanism from which intermediates and catalytically active species have been identified.

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عنوان ژورنال:
  • Chemical communications

دوره 50 14  شماره 

صفحات  -

تاریخ انتشار 2014