Signal amplification and transduction by photo-activated catalysis.
نویسندگان
چکیده
A simple flavin-based catalytic system is able to transform light into chemical output with amplified response utilizing a Cu(I)-catalyzed cycloaddition reaction.
منابع مشابه
Signal transduction and amplification through enzyme-triggered ligand release and accelerated catalysis† †Electronic supplementary information (ESI) available: Experimental procedures, compound characterisation data and copies of NMR spectra for novel compounds. See DOI: 10.1039/c5sc01588j Click here for additional data file.
Signal transduction and signal amplification are both important mechanisms used within biological signalling pathways. Inspired by this process, we have developed a signal amplification methodology that utilises the selectivity and high activity of enzymes in combination with the robustness and generality of an organometallic catalyst, achieving a hybrid biological and synthetic catalyst cascad...
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ورودعنوان ژورنال:
- Chemical communications
دوره 45 شماره
صفحات -
تاریخ انتشار 2006