Di-μ-thiocyanato-κ4 N:N-bis({2,4-dibromo-6-[2-(methylamino)ethyliminomethyl]phenolato-κ3 N,N′,O}nickel(II))
نویسنده
چکیده
The title complex, [Ni(2)(C(11)H(11)Br(2)N(2)O)(2)(NCS)(2)], is a thio-cyanate-bridged dinuclear nickel(II) complex. The asymmetric unit contains two molecules. Both Ni atoms in each molecule have a square-pyramidal coordination geometry, and each center is bound by one O and two N atoms of one Schiff base ligand and by one N atom of a bridging thio-cyanate ligand, which define the basal planes. N atoms from the bridging thio-cyanate ligands occupy the apical positions.
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Di-μ-thiocyanato-κ4 N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ3 O 1,N,N′}copper(II))
The title thio-cyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridging thio-cyanate ligands, forming a square-pyramidal geometry. Beside the two thio-cyanate bridges,...
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