2-[4-(Methylsulfonyl)phenyl]acetonitrile
نویسندگان
چکیده
In the title compound, C(9)H(9)NO(2)S, the benzene ring and the acetonitrile group are approximately coplanar, with a C-C-C-C torsion angle of 1.1 (3)° between them. In the crystal, mol-ecules are linked via inter-molecular C-H⋯O hydrogen bonds into layers parallel to (001).
منابع مشابه
[4-(Methylsulfonyl)phenyl]acetic acid
In the crystal structure of the title compound, C(9)H(10)O(4)S, centrosymmetrically related mol-ecules are linked into dimers by inter-molecular O-H⋯O hydrogen bonds. Unconventional C-H⋯O hydrogen-bond inter-actions are also present, connecting dimers into a three-dimensional network.
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In the title compound, C(23)H(19)FO(5)S(2), two of the phenyl ring C atoms and a sulfonyl O atom of the phenyl(methylsulfonyl) group are disordered over two positions with occupancies 0.522 (17):0.478 (17). The methyl-phenyl and fluoro-phenyl rings are essentially planar, with maximum deviations of 0.0059 (8) and 0.0047 (9) Å, respectively. The crystal packing is stabilized by C-H⋯F inter-actions.
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In the title compound, C(12)H(17)NO(5)S, the orientations of the 2-ethyl-2-amino-3-hy-droxy-propano-ate group and the 4-methyl-sulfonyl moiety towards the aromatic ring are periplanar and (-)-anti-clinal, respectively. In the crystal packing, the dominant inter-action is O-H⋯N hydrogen bonding, which generates a chain running along [100]. N-H⋯O and C-H⋯O interactions are also observed.
متن کامل(R)-[(R)-3-Benzyl-2-oxooxazolidin-4-yl][4-(methylsulfonyl)phenyl]methyl acetate
The structure of the title compound, C20H21NO6S, is of inter-est with respect to its anti-bacterial properties. The oxazolidine ring makes dihedral angles of 79.63 (14) and 56.16 (12)° with the phenyl and benzene rings, respectively, while the phenyl and benzene rings make a dihedral angle of 64.37 (13)°. In the crystal, non-classical C-H⋯O hydrogen bonds link adjacent mol-ecules along the c axis.
متن کامل{4′-[4-(4,4′-Bipyridin-1-ylmethyl)phenyl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis(perchlorate) acetonitrile disolvate sesquihydrate
The asymmetric unit of the title compound, [PtCl(C(32)H(24)N(5))](ClO(4))(2)·2CH(3)CN·1.5H(2)O, comprises two unique Pt(II) complex cations, four perchlorate anions, four acetonitrile solvent mol-ecules and three water mol-ecules. The Pt atom is four-coordinated by a tridentate chelating 2,2':6',2''-terpyridine ligand and a chloride ion in a square-planar geometry with modest distortion imposed...
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