281e Kinetic Modeling of the Vinyl Chloride Suspension Polymerization
نویسندگان
چکیده
The physical properties of the polymer product determine to a large extent its processability and applications. A large number of properties are directly related to the molecular mass distribution (MMD) of the polymer product. Besides the MMD, the polymer microstructure also plays an important role and influences to a large extent the thermal stability of the polymer product. Most of the thermal degradation reactions start at thermally labile structural segments of the polymer chains, i.e. internal allylic and tertiary chloride structural defects, formed during polymerization (cfr. Figure 1).
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