A novel method for the synthesis of solvent-free Mg(B3H8)2.
نویسندگان
چکیده
This communication presents a novel and solvent-free method to synthesise Mg(B3H8)2 via the gas-solid reaction between B2H6 and Mg2NiH4, which overcomes the limitations of wet chemical methods requiring solvent removal.
منابع مشابه
Volatile magnesium octahydrotriborate complexes as potential CVD precursors to MgB2. Synthesis and characterization of Mg(B3H8)2 and its etherates.
The solid-state reaction of MgBr2 and NaB3H8 at 20 degrees C, followed by sublimation at 80 degrees C and 0.05 Torr, affords Mg(B3H8)2 as a white solid. Similar reactions with MgBr2(Et2O) and MgBr2(Me2O)1.5 afford the crystalline ether adducts Mg(B3H8)2(Et2O)2 and Mg(B3H8)2(Me2O)2, respectively. In contrast, reactions of MgBr2 with NaB3H8, the presence of excess solvent result in the formation ...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 45 9 شماره
صفحات -
تاریخ انتشار 2016