A new type of paddle-wheel coordination complex.
نویسندگان
چکیده
In the presence of Na(+) ions, the reaction of the ligand 2-hydroxy-1,3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-benzene, H5L4, with M(AcO)2 salts (M = Mn, Co) gathers the conditions for the assembly of coordination complexes (NBu4)3[M2Na2(H2L4)3] (M = Mn(II) 1 and Co(II) 2), which exhibit a new paddle-wheel structure. The features of this new category of compounds are discussed as well as their magnetic properties and solution behaviour.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 34 شماره
صفحات -
تاریخ انتشار 2013