Biomimetic Hydroxyapatite Growth on Functionalized Surfaces of Ti-6Al-4V and Ti-Zr-Nb Alloys
نویسندگان
چکیده
A biomimetic approach for coating titanium-containing alloys with hydroxyapatite (HA) is reported in the article. Two types of Ti-containing alloys were chosen as an object for coating: Ti-6Al-4V (recommended for orthopedic application) and a novel highly biocompatible Ti-Zr-Nb alloy, with good mechanical compatibility due to a modulus that is more close to that of human bones (E ≈ 50 GPa instead of 110 GPa in Ti-6Al-4V). Coating process was carried out in a 10×-concentrated simulated body fluid (SBF)-synthetic analog of human body plasma. The effect of oxidized and carboxylated alloy surface on formation of biomimetic hydroxyapatite has been studied. By XRD, we found influence of thermal conditions on HA crystal formation and size. SEM images and Fourier transform infrared confirmed that hydroxyapatite with different morphology, crystallinity, and Ca/P ratio formed on metallic surfaces. X-ray photoelectron spectroscopy showed that in the Ti-6AL-4V sample the observed Ca/P ratio reach 0.97, whereas in the Ti-Zr-Nb sample the observed Ca/P ratio reach 1.15.
منابع مشابه
An investigation on metallurgical and mechanical properties of vacuum brazed Ti-6Al-4V to 316L stainless steel using Zr-based filler metal
Both Ti-6Al-4V and 316L stainless steels are widely used as engineering alloys. Fusion welding of these two alloys is not easily possible due to their incomplete solubility in each other. Brazing is one of the best choices for joining dissimilar alloys. In this study, wettability experiments were done at 940 and 970 ºC for 5, 15 and 30 min. Also, joining of these two alloys was carried out at 9...
متن کاملOsteoblastic behavior to zirconium coating on Ti-6Al-4V alloy
PURPOSE The purpose of this study was to assess the surface characteristics and the biocompatibility of zirconium (Zr) coating on Ti-6Al-4V alloy surface by radio frequency (RF) magnetron sputtering method. MATERIALS AND METHODS The zirconium films were developed on Ti-6Al-4V discs using RF magnetron sputtering method. Surface profile, surface composition, surface roughness and surface energy...
متن کاملTi-6Al-4V Synthesized by Mechanical Alloy Method and Mechanical and Bioactivity Properties of Ti-6Al-4V/HA-Clay Nano composite
Nowadays, titanium-based alloys are among the most attractive metallic materials for biomedical applications (as implants) due to their non-biodegradability, low density, good mechanical properties as well as their good biocompatibility. Hydroxyapatite (Ca10 (PO4)6(OH)2, HA) has been widely used for biomedical applications due to its bioactive, biocompatible and osteoconductive properties. Firs...
متن کاملComparison of Fatigue Properties and Fatigue Crack Growth Rates of Various Implantable Metals
The fatigue strength, effects of a notch on the fatigue strength, and fatigue crack growth rate of Ti-15Zr-4Nb-4Ta alloy were compared with those of other implantable metals. Zr, Nb, and Ta are important alloying elements for Ti alloys for attaining superior long-term corrosion resistance and biocompatibility. The highly biocompatible Ti-15Zr-4Nb-4Ta alloy exhibited an excellent balance between...
متن کاملMesoporous Bioactive Glass Functionalized 3D Ti-6Al-4V Scaffolds with Improved Surface Bioactivity
Porous Ti-6Al-4V scaffolds fabricated by means of selective laser melting (SLM), having controllable geometrical features and preferable mechanical properties, have been developed as a class of biomaterials that hold promising potential for bone repair. However, the inherent bio-inertness of the Ti-6Al-4V alloy as the matrix of the scaffolds results in a lack in the ability to stimulate bone in...
متن کامل