The Mechanism of the Interfacial Charge and Mass Transfer during Intercalation of Alkali Metal Cations

نویسندگان

  • Edgar Ventosa
  • Bianca Paulitsch
  • Philipp Marzak
  • Jeongsik Yun
  • Florian Schiegg
  • Thomas Quast
  • Aliaksandr S. Bandarenka
چکیده

Intercalation of alkali metal cations, like Li+ or Na+, follows the same three-stage mechanism of the interfacial charge and mass transfer irrespective of the nature of the electrolyte, electrolyte composition or electrode material.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Topological Analysis of Theoretical Charge Density of Alkali Metal Cations (LC, Na+, le)ICrown Ether (18e6) Complexes

The DO1(18c6)fi (MwLi. Na. K and I 8c6=18-crown-6) complexes have been chosen as the model systems toinvestigate the nature of chemical bonds between alkali metal cations and large mffitidentaie orgmnic ligands.The B3LYP/6-3I+G(d,p) level of calculation has been used for obtaining equilibrium geernetnes and p(r)functions (electron density distributions). By the aid of fundamental physical theor...

متن کامل

Investigation of NMR Shielding Tensors of Para-Sulfonato-calix 141 arene Complexation with some of Alkali metal atoms

Calixarenes are a readily available and important class of macrocycles in supramolecularchemistry. Calixarenes have generated considerable interest due to their basket shaped structureand as useful building blocks to synthesize selective receptors for the guest species, notably alkali,alkaline earth, lanthanide and transition metal cations. In this work studied on the complexingproperties of a ...

متن کامل

A TRANSIENT TWO-DIMENTIONAL INVERSE ESTIMATION OF THE METAL-MOLD HEAT TRANSFER COEFFICIENT DURING SQUEEZE CASTING of AL-4.5WT%CU

In this paper, a transient, two-dimensional and nonlinear inverse heat conduction problem in solidification process is considered. Genetic algorithm is applied for the identification of the interfacial heat transfer coefficients during squeeze casting of commercial aluminum alloy (Al-4.5wt%Cu) by assuming a priori information regarding the functional form of the unknown heat transfer coefficien...

متن کامل

Selective and low temperature transition metal intercalation in layered tellurides

Layered materials embrace rich intercalation reactions to accommodate high concentrations of foreign species within their structures, and find many applications spanning from energy storage, ion exchange to secondary batteries. Light alkali metals are generally most easily intercalated due to their light mass, high charge/volume ratio and in many cases strong reducing properties. An evolving ar...

متن کامل

The pH effect on complexation of Alkali metal cation by p-sulfonatocalix (4) arene in aqueous solution

The complexation of Alkali metal cations by the water-soluble p-sulfonic acid calix(4)arenewas thermodynamically characterized using spectrophotometeric data which are consistentwith the formation of a 1:1 complex resulting from electrostatic interactions between thesulfonato groups and alkali metal cations. In this study, we determined the formationconstants (log K) of the complexes and have c...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 3  شماره 

صفحات  -

تاریخ انتشار 2016