The case of the nonionic alkylphenol ethoxylates in the Mediterranean Sea region: is there a problem?
نویسندگان
چکیده
The concentration profiles of the potential endocrine disrupting nonionic alkylphenol ethoxylate (APEO) surfactants in Israel's rivers, groundwaters and coastal water of the eastern Mediterranean Sea, were found to be within the range of 12.5-74.6, trace - 20.2 and 4.2-25.0 microg/L respectively. Determination of the APEO's homologic distribution revealed "skewing" towards the more toxic shorter-chain ethoxylates. Egg production of zebrafish, Danio rerio, exposed to these actually found the environmental concentrations range of the APEOs decreased, after 20 days, to 89.6+/-2.1, 84.7+/-3.9 and 76.9+/-2.2% of the baseline levels, compared with control, in concentrations of 10, 25 and 75 microg/L respectively. These results suggest that, (a) there is a potential health problem, particularly in countries in which the "hard"/environmentally persistent APEOs are still in use; and (b) the related health-risk is seasonally-dependent, particularly in semi-arid regions where the fluctuations in the water quantities in surface- and groundwater are substantial.
منابع مشابه
Estuarine and coastal zone marine pollution by the nonionic alkylphenol ethoxylates endocrine disrupters: is there a potential ecotoxicological problem?
The nonionic biodegradation-resistant ("hard") alkylphenol ethoxylate (APEO) surfactants and their degradation products are known endocrine disrupting chemicals (EDCs). We report here the findings concerning the APEOs concentrations and homologic distribution profiles in Israel's estuarine and coastal zone seawater to serve as a case study. The concentrations in sewage-containing rivers, estuar...
متن کاملWST 50.5-H42 corr
The concentration profiles of the potential endocrine disrupting nonionic alkylphenol ethoxylate (APEO) surfactants in Israel’s rivers, groundwaters and coastal water of the eastern Mediterranean Sea, were found to be within the range of 12.5–74.6, trace – 20.2 and 4.2–25.0 μg/L respectively. Determination of the APEO’s homologic distribution revealed “skewing” towards the more toxic shorter-ch...
متن کاملAlkylphenol and alkylphenol-ethoxylates in carp, water, and sediment from the Cuyahoga River, Ohio.
The occurrence of alkylphenol and alkylphenol ethoxylates (APEs) was determined over a 74-mile length of the Cuyahoga River, Ohio. Measurable levels of both the octyl and nonyl forms of these abundantly used nonionic surfactants were observed with the nonylphenol (NP) plus nonylphenol ethoxylates (NPEs) typically accounting for greater than 90% of the total APEs in each sample. For all media (w...
متن کاملThe Analysis and modeling of widespread anomalies of rainfall in entire West of Iran in relation with the behaviors of Mediterranean Pressure centers
Climate control centers in each area are diverse and understanding how they relate to the atmospheric components of the Earth's surface contribute to prediction of climate fluctuations. In this study, by using Pearson's correlation and multivariate regression in a thirty-year period (1961-2010), the relationship between widespread rainfall anomalies in entire of Iran west with temperature a...
متن کاملInfluence of Hydrophobe Structure on Biodegradation Pathways of Nonionic Ethoxylates
The structure of the hydrophobe in alcohol ethoxylates (AE) and alkylphenol ethoxylates (APE) has a significant influence on the biodegradation pathways and biodegradation rates of these nonionic surfactants in bacterial inocula present in waste treatment plants. APE undergo initial microbial attack at the terminal part of the polyoxyethylene (POE) chain followed by a shortening of the POE chai...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Water science and technology : a journal of the International Association on Water Pollution Research
دوره 50 5 شماره
صفحات -
تاریخ انتشار 2004