Trigonal prismatic Cu(I) and Ag(I) pyrazolato nanocage hosts: encapsulation of S8 and hydrocarbon guests.

نویسندگان

  • Peng-Cheng Duan
  • Zhao-Yang Wang
  • Jing-Huo Chen
  • Guang Yang
  • Raphael G Raptis
چکیده

Two neutral hexanuclear trigonal prismatic cage molecules have been synthesized by coupling two planar triangular M3pz3-panels, M = Cu(I) and Ag(I), in eclipsed geometry. The ~230 Å(3) cage volume can be either vacant or occupied by neutral guests. The crystal structures of the M6-cyclohexane and Ag6-S8 host-guest species have been determined.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 42  شماره 

صفحات  -

تاریخ انتشار 2013