Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols.
نویسندگان
چکیده
The unprecedented homogeneous hydrogenation of cyclic di-esters, in particular biomass-derived glycolide and lactide, to the corresponding 1,2-diols is catalyzed by Ru(II) PNN (1) and Ru(II) CNN (2) pincer complexes under mild hydrogen pressure and (in the case of 1) neutral conditions. No racemization was observed when a chiral di-ester was used.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 8 شماره
صفحات -
تاریخ انتشار 2012