Responsive fluorinated lanthanide probes for 19F magnetic resonance spectroscopy.

نویسندگان

  • P Kanthi Senanayake
  • Alan M Kenwright
  • David Parker
  • Susanna K van der Hoorn
چکیده

The introduction of CF(3) reporter groups close to the paramagnetic centre in macrocyclic lanthanide(iii) complexes allows faster acquisition of (19)F magnetic resonance data, and amplifies chemical shift non-equivalence, as exemplified by the definition of ratiometric chemical shift probes for pH and, in principle, enzyme activity.

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عنوان ژورنال:
  • Chemical communications

دوره 28  شماره 

صفحات  -

تاریخ انتشار 2007