Gas phase nucleophilic substitution
نویسندگان
چکیده
The literature on gas phase nucleophilic substitution reactions at aliphatic carbon has been reviewed. The emphasis has been on journal articles published in the period 1990–2001. The present review outlines our current understanding of concepts such as potential energy surfaces, structure–energy relationships, microsolvation, and dynamical and mechanistic details based on both experimental and theoretical evidence. The accuracy of various theoretical schemes for calculating potential energy surfaces has been assessed. A critical account on mechanistic concepts used in the literature is given. (Int J Mass Spectrom 214 (2002) 277–314) © 2002 Elsevier Science B.V. All rights reserved.
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