Diphenyl[(phenylsulfanyl)methyl]-λ5-phosphanethione
نویسنده
چکیده
The title compound, C19H17PS2, results from the direct deprotonation of di-phenyl-methyl-phosphine sulfide and subsequent reaction with diphenyl di-sulfide. The C-P and C-S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P-C-S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the di-phenyl-methyl moiety is 69.46 (7)°. No distinct inter-molecular inter-actions are present in the crystal structure.
منابع مشابه
N-Diphenylphosphanyl-N-{[diphenyl(2-pyridylimino)-λ5-phosphanyl]methyl}pyridin-2-amine
In the title compound, C(35)H(30)N(4)P(2), the diphenyl-phosphanyl and diphen-yl(2-pyridyl-imino)-λ(5)-phosphanyl groups are attached to the central methyl C atom with a P-C-N angle of 114.09 (16)°. The mol-ecules stack along the b axis and inter-connect through C-H(pyrid-yl)⋯N(pyrid-yl) inter-actions, forming an infinite chain structure. The parallel chains are further inter-connected via C-H(...
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