Microwave synthesis of hybrid inorganic-organic porous materials: phase-selective and rapid crystallization.
نویسندگان
چکیده
Microwave synthesis of two porous nickel glutarates was compared with conventional hydrothermal synthesis. The cubic nickel glutarate, [Ni20(C5H6O4)20(H2O)8] x 40 H2O (1), was synthesized by conventional electrical heating in several hours or days, depending on synthesis temperature. Crystallization was greatly accelerated by microwave irradiation, in which more stable, tetragonal nickel glutarate, [Ni22(C5H6O4)20(OH)4(H2O)10] x 38 H2O (2), was formed within a few minutes, suggesting the efficiency of the microwave technique in the synthesis of porous hybrid materials. The cubic phase 1 is formed preferentially at low pH, low temperature, and especially under conventional electrical heating. In contrast, the tetragonal phase 2 is obtained favorably at high pH, high temperature, and especially with microwave irradiation. This work demonstrates that the microwave method provides not only the very fast synthesis of a hybrid material, but also the possibility to discover a new porous hybrid material not yet identified by conventional hydrothermal synthesis. The hydrothermal formation of metal-organic hybrid materials in a matter of minutes is an important step towards developing commercially viable routes for producing this valuable class of materials.
منابع مشابه
Introduction, synthesis procedures, and applications of organic-inorganic hybrid nanoflowers in biosciences
Organic-inorganic hybrid nanoflowers with flower-like morphology are new nanostructures comprising organic and inorganic components. In general, the organic component of hybrid nanoflowers mostly consists of proteins, DNA, RNA, plant extracts, metabolites, and natural polymers; and the inorganic component composes of various metal phosphates, including copper, calcium, manganese, iron, zinc, co...
متن کاملNano-colloidal silica-tethered polyhedral oligomeric silsesquioxanes with eight branches of 3-aminopropyltriethoxysilane as high performance catalyst for the preparation of furan-2(5H)-ones
An efficient and rapid method for the synthesis of 3,4,5-substituted furan-2 (5H)-ones has been achieved through a three-component reaction of aniline, dialkyl acetylenedicarboxylate, and aromatic aldehydes using nano-colloidal silica-tethered polyhedral oligomeric silsesquioxanes with eight branches of 3-aminopropyltriethoxysilane (nano-colloidal silica @APTPOSS) as a superior catalyst under m...
متن کاملConductive Polythiophene Nanoparticles Deposition on Transparent PET Substrates: Effect of Modification with Hybrid Organic-inorganic Coating (RESEARCH NOTE)
In this work, Poly(ethyleneterephthalate) (PET) substrate was treated using KOH solution and was modified using hybrid O-I coating containing PCL )polycaprolactone( as organic phase and TEOS )tetraethoxysilane( as inorganic phase. The coating was prepared through a sol-gel process and applied on the surface by dip coater. Then, electrically conducting polythiophene (PTh) nanoparticles were depo...
متن کاملSynthesis of Semiconducting Functional Materials in Solution: From II-VI Semiconductor to Inorganic-Organic Hybrid Semiconductor Nanomaterials
This Feature Article provides a brief overview of the latest development and emerging new synthesis solution strategies for II–VI semiconducting nanomaterials and inorganic-organic semiconductor hybrid materials. Research on the synthesis of II–VI semiconductor nanomaterials and inorganic–organic hybrid semiconducting materials via solution strategies has made great progress in the past few yea...
متن کاملOne-pot synthesis of hierarchical porous layered hybrid materials based on aluminosilicate sheets and organic functional pillars. Journal of Materials Chemistry A. 2(45):19360-19375. doi:10.1039/c4ta04742g
Layered hybrid materials (LHMs) based on ordered silicoaluminate sheets linked with organic fragments, perpendicularly located and stabilized in the interlayer space, were synthesized by one-pot direct hydrothermal process, in absence of structural directing agents (SDAs), and using bridged silsesquioxanes as organosilicon precursors. By following the synthesis described here, the preliminary p...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemistry
دوره 12 30 شماره
صفحات -
تاریخ انتشار 2006