1,1-Dibenzyl-3-(3-chlorobenzoyl)thiourea
نویسندگان
چکیده
In the title compound, C(22)H(19)ClN(2)OS, the thiono and carbonyl groups are trans positioned with respect to a partially double C-N bond. The amide group is twisted relative to the thio-urea fragment, forming a dihedral angle of 46.75 (11)°. In the crystal, inter-molecular N-H⋯S and C-H⋯O hydrogen bonds link the mol-ecules into a one-dimensional polymeric structure parallel to the c axis.
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1,1-Dibenzyl-3-(4-fluorobenzoyl)thiourea
In the title compound, C(22)H(19)FN(2)OS, the 2-fluoro-benzoyl group adopts a trans conformation with respect to the thiono S atom across the N-C bond. In the crystal, inter-molecular N-H⋯S, C-H⋯S and C-H⋯O hydrogen bonds link the mol-ecules, forming a two-dimensional network parallel to (101).
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In the title compound, C12H9ClN4OS, the carbonyl group is at a cis position with respect to the thio-urea unit. The dihedral angle between the phenyl and pyrimidine ring is 16.49 (6)°. An intra-molecular N-H⋯N hydrogen bond stabilizes the mol-ec-ular conformation. In the crystal, N-H⋯N, C-H⋯O and C-H⋯S hydrogen bonds generate chains along the bc axis.
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