Unravelling phenomenon of internal rotation in B13+ through chemical bonding analysis.

نویسندگان

  • Gerardo Martínez-Guajardo
  • Alina P Sergeeva
  • Alexander I Boldyrev
  • Thomas Heine
  • Jesus M Ugalde
  • Gabriel Merino
چکیده

We describe and explain the fluxionality of B(13)(+). The chemical bonding analysis shows that the inner triangle of B(13)(+) is bound to the peripheral ring by delocalized bonds only, allowing a quasi-free rotation of the inner ring.

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عنوان ژورنال:
  • Chemical communications

دوره 47 22  شماره 

صفحات  -

تاریخ انتشار 2011