Pentafulvene-derived η3-allyltitanocenes as intermediates for the stereoselective functionalization of 5-membered carbocycles.
نویسندگان
چکیده
Allyltitanocene complexes can be generated by reacting pentafulvenes with DIBAL-H and Cp2TiCl2. Their coupling with aldehydes affords homoallylic alcohols in a highly regio- and stereoselective manner. The potential of this method for the stereoselective synthesis of cyclopentane derivatives is illustrated.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 40 شماره
صفحات -
تاریخ انتشار 2013