Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(iv) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes.
نویسندگان
چکیده
The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(iv) complexes, where the reactivity, chemoselectivity, and mechanism were strongly influenced by the ligand environment of the iron center.
منابع مشابه
Cataliticoxidation of benzyl alcohol by Cu(II) polypyridyl complexes
Two polypyridyl copper(II) complexes, [Cu(phen)(phen-dione)Cl]Cl (1) and [Cu(bpy) (phen-dione)Cl]Cl (2), (where Phen =1,10-phenanthroline, bpy =2,2'-bipyridine and Phen-dione = 1,10-phenanthroline-5,6-dione), were used as efficient catalysts for the oxidation of benzyl alcohol to benzaldehyde. The effects of various parameters such as reaction temperature, reaction time, etc. were studied. The ...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 47 10 شماره
صفحات -
تاریخ انتشار 2018