(4,4′,6,6′-Tetra-tert-butyl-2,2′-{[2-(di­methyl­amino)­ethyl]­nitrilo­bis­(methyl­ene)}diphenolato)dioxidomolyb­denum(VI) chloro­form monosolvate

نویسندگان

  • Xiangyang Lei
  • Nagasree Chelamalla
چکیده

In the title compound, [Mo(C(34)H(54)N(2)O(2))O(2)]·CHCl(3), the molybdenum(VI) ion exhibits a cis-dioxide distorted octa-hedral geometry. Two anionic phenolate O-atom donors and two neutral N-atom donors of the ligand are trans and cis, respectively. The Mo=O bond lengths and the O=Mo=O bond angle are typical for six-coordinated dioxomolyb-denum(VI) complexes. The Mo-N bond lengths are longer than 2.30 Å, as expected for a trans O=Mo-N structure.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011