Acetonitriletrichloridobis(cyclohexyldiphenylphosphane)rhodium(III) acetonitrile disolvate
نویسندگان
چکیده
In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol-ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol-ecule. The Rh(III) atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile mol-ecule in a distorted octa-hedral geometry. Intra-molecular C-H⋯Cl inter-actions are observed. The uncoordinated acetonitrile mol-ecule is disordered over two sites with occupancies of 0.588 (4) and 0.412 (4).
منابع مشابه
Spectroelectrochemical Study of some //3-Oxo-//-acetato Trinuclear Rhodium(III) and Iridium(III) Complexes
Masato Tominaga, Isao Taniguchi Department of Applied Chemistry, Faculty of Engineering, Kumamoto University, Kurokami, Kumamoto 860, Japan Dedicated to Prof. Hitoshi Ohtaki on the occasion o f his 60th birthday Z. Naturforsch. 50b, 551-557 (1995); received October 5, 1994 Trinuclear Complexes, Rhodium Complexes, Iridium Complexes, dn-ipji Interaction, Spectroelectrochemistry, Mixed Valence Sta...
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