{2-[(Dimethylamino)methyl]phenyl}bis(4-methylphenyl)bismuthane
نویسندگان
چکیده
The title compound, [Bi(C(7)H(7))(2)(C(9)H(12)N)], was obtained by treating chlorodi(p-tol-yl)bis-muthane with o-lithio-N,N-dimethyl-benzyl-amine. An intra-molecular Bi⋯N nonbonding inter-action is observed in the distorted trigonal triaryl-bis-muth coordination of the title compound.
منابع مشابه
Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ3-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate
The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn-N bonds [2.517 (4) Å], but the protonated dimethylamino groups in the periphery of the complex show no intera...
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