Estimating the water content of hydrated minerals using reflectance spectroscopy II. Effects of particle size

Visible-near infrared reflectance spectra for five particle size fractions of a Hawaiian palagonite (HWMK101) and a nontronite (ferruginous smectite, Clay Minerals Society source clay SWa-1) were measured under ambient, purged, and heated conditions to characterize the effects of surface and volume scattering on the relationship between absolute H2O content and the strength of the 3 μm absorption feature. Both materials were ground and dry sieved to particle sizes of <25, 25–45, 45–75, 75–125, and 125–250 μm. Particles of the bulk palagonite have an approximate bimodal distribution consisting of small, amorphous particles <5 μm in diameter mixed with crystalline and glass particles <1 mm in diameter, whereas the nontronite particles are polycrystalline aggregates. We find that band parameters value relating the strength of the 3 μm hydration feature to water content increase with particle size for a given water content, regardless of whether reflectance or single scattering albedo spectra are used. Spectra generally increase in reflectance as particle size decreases, a result of the relative increase in volume to surface scattering. Spectra of large particles are commonly saturated in the 3 μm region due to an increase in optical path length, making an accurate estimate of water content indeterminate until the samples dehydrate to the volume-scattering regime. We find that the presence of fines in several of the size fractions of palagonite cause their spectra to be representative of the finest fraction rather than the mean particle size. The nontronite spectra appear to be representative of an effective particle size within the range of the sieved size fractions. Many planetary surfaces are expected to have a large number of small particles which can dominate their spectral signature. Our results for particles <45 μm provide a reasonable model for estimating the H2O content of hydrated asteroids and regions of Mars. © 2007 Elsevier Inc. All rights reserved.