Urea-based constructs readily amplify and attenuate nonlinear optical activity in response to H-bonding and anion recognition.

نویسندگان

  • Deepak Asthana
  • Ravindra Pandey
  • Pritam Mukhopadhyay
چکیده

Urea-based molecular constructs are shown for the first time to be nonlinear optically (NLO) active in solution. We demonstrate self-assembly triggered large amplification and specific anion recognition driven attenuation of the NLO activity. This orthogonal modulation along with an excellent nonlinearity-transparency trade-off makes them attractive NLO probes for studies related to weak self-assembly and anion transportation by second harmonic microscopy.

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عنوان ژورنال:
  • Chemical communications

دوره 49 5  شماره 

صفحات  -

تاریخ انتشار 2013