Synthesis and characterization of azobenzene-confined porphyrins.
نویسندگان
چکیده
A versatile synthetic method has been developed to incorporate photochromic azobenzene moieties into tetraphenylporphyrin frameworks in an orthogonal fashion, positioning the phenylazo substituents above and below the plane of the macrocycle. Surprisingly, photoisomerization is completely suppressed in the resulting azobenzene-confined porphyrins.
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 71 20 شماره
صفحات -
تاریخ انتشار 2006