The improved synthesis of carbonated soybean oil using supercritical carbon dioxide at a reduced reaction time{{
نویسندگان
چکیده
We have demonstrated an improved synthesis of a cyclic carbonate of soybean oil (CSO) utilizing supercritical carbon dioxide (CO2) as the solvent. Because the mutual solubility of supercritical CO2 and soybean oil is significantly higher than that of gaseous CO2 and soybean oil, our method synthesizes the material in y1/3 of the reaction time reported in the literature. We have also demonstrated a catalyst removal method for our system based on the simple Hofmann elimination reaction, reducing the need for organic solvent extraction. CSO is a potential petroleum replacement, and may be useful in the synthesis of polymers based on bio-resources.
منابع مشابه
Continuous Synthesis of Oleyl Oleate in Supercritical Carbon Dioxide using Solid p-Toluenesulfonic Acid as Catalyst
Supercritical carbon dioxide (SC-CO2) was used as solvent to synthesize oleyl oleate as an analog of Jojoba oil from oleic acid and oleyl alcohol with high conversion (100%) of the acid into ester in a short time of 100 min. Utilizing a low cost solid catalyst, p-toluenesulfonic acid monohydrate (PTSA), the esterification reaction was performed, without any prior preparation step...
متن کاملPhase-Transfer Catalysed Epoxidation of Soybean Oil Using Hydrogen Peroxide and Supercritical Carbon Dioxide
Epoxidized vegetable oils are the product of vegetable oil epoxidation reactions. Since the epoxidized vegetable oil is a nonpoisonous plasticizer, it has been wildly used in the plastic packaging of food and medicine. Among the various epoxidized vegetable oils, the application of epoxidized soybean oil is broader than others. Nowadays, it’s the third largest category of plasticizers. However,...
متن کاملSynthesis of polyvinyl pyridine/C60 conjugates in supercritical carbon dioxide*
In the present investigation efforts have been made to synthesis polyvinyl pyridine (PvPy) /C60 conjugates through 2, 2-azobisisobutyronitrile (AIBN) initiated insitu polymerization of PvPy in scCO2.The process of synthesis was monitored under different reaction conditions ranging 1200-1800psi, 60-90 oC over 6 hours. The progress of polymerization was monitored rheoviscometrically. The concentr...
متن کاملFrom oligomers to molecular giants of soybean oil in supercritical carbon dioxide medium: 1. Preparation of polymers with lower molecular weight from soybean oil.
Polymers with a low molecular weight derived from soybean oil have been prepared in a supercritical carbon dioxide medium by cationic polymerization. Boron trifluoride diethyl etherate was used as an initiator. Influences of polymerization temperature, amount of initiator, and carbon dioxide pressure on the molecular weight were investigated. It is shown that the higher polymerization temperatu...
متن کامل