nBu4NI-catalyzed oxidative imidation of ketones with imides: synthesis of α-amino ketones.
نویسندگان
چکیده
nBu4NI-Catalyzed oxidative imidation of ketones and imides for the synthesis of α-amino ketones were realized for the first time. The methodology is characterized by its wide substrate scope even for acetone with readily available phthalimide, saccharin and succinimide, which opens a new pathway for direct imidation of ketones.
منابع مشابه
nBu4NI-catalyzed direct synthesis of α-ketoamides from aryl methyl ketones with dialkylformamides in water using TBHP as oxidant.
A novel and easy practical direct synthesis of α-ketoamides has been developed without metals in water. This procedure was catalyzed by nBu(4)NI using TBHP as oxidant from simple substrates, aryl methyl ketones and dialkylformamides.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 18 شماره
صفحات -
تاریخ انتشار 2014