A fully complementary, high-affinity receptor for phosphate and sulfate based on an acyclic tris(urea) scaffold.
نویسندگان
چکیده
A fully complementary tris(urea) receptor for phosphate and sulfate anions has been developed by mimicking the scaffold of terpyridine which shows very high affinities and selectivities toward the tetrahedral anions.
منابع مشابه
Synthesis and anion binding studies of tris(3-aminopropyl)amine-based tripodal urea and thiourea receptors: Proton transfer-induced selectivity for hydrogen sulfate over sulfate.
Tris(3-aminopropyl)amine-based tripodal urea and thiourea receptors, tris([(4-cyanophenyl)amino]propyl)urea (L1) and tris([(4-cyanophenyl)amino]propyl)thiourea (L2), have been synthesized and their anion binding properties have been investigated for halides and oxoanions. As investigated by 1H NMR titrations, each receptor binds an anion with a 1:1 stoichiometry via hydrogen-bonding interaction...
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 29 شماره
صفحات -
تاریخ انتشار 2010