Combination between [B-α-SiW9O34] unit and triangular inorganic Ni6 core under hydrothermal conditions: from monomer to rare dimer with malposed dodeca-nickel centers.
نویسندگان
چکیده
The hydrothermal reactions of α-K(4)SiW(12)O(40) with NiCl(2)·6H(2)O yielded two unprecedented silicotungstates containing a triangular inorganic Ni(6) core. Furthermore, Na(2)[Ni(6)(μ(3)-OH)(3)(H(2)O)(9)SiW(9)O(34)](2)·17H(2)O (1) presents a rare dimer, in which two SiW(9) units sandwich double Ni(6) cores by W-O-Ni linking instead of conventional Ni-O-Ni.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 2 شماره
صفحات -
تاریخ انتشار 2013