(2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate
نویسندگان
چکیده
The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethyl-formamide solvent mol-ecule is disordered over two orientations with site occupancies of 0.684 (3) and 0.316 (3). The two N atoms of the hydrazinecarboxamide group are involved in inter-molecular N-H⋯O hydrogen bonds in which the dimethyl-formamide O atom acts as acceptor. The structure also features π-π inter-actions, with a centroid-centroid distance of 3.6561 (13) Å. Classical and non-classical intra-molecular O-H⋯N and C-H⋯O hydrogen bonds are also present.
منابع مشابه
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