Polymer size in dilute solutions in the good-solvent regime.

نویسندگان

  • Sergio Caracciolo
  • Bortolo Matteo Mognetti
  • Andrea Pelissetto
چکیده

We determine the density expansion of the radius of gyration, of the hydrodynamic radius, and of the end-to-end distance for a monodisperse polymer solution in good-solvent conditions. We consider the scaling limit (large degree of polymerization), including the leading scaling corrections. Using the expected large-concentration behavior, we extrapolate these low-density expansions outside the dilute regime, obtaining a prediction for the radii for any concentration in the semidilute region. For the radius of gyration, comparison with field-theoretical predictions shows that the relative error should be at most 5% in the limit of very large polymer concentrations.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Influence of solvent quality on polymer solutions: a Monte Carlo study of bulk and interfacial properties.

The effect of solvent quality on dilute and semidilute regimes of polymers in solution is studied by means of Monte Carlo simulations. The equation of state, adsorption near a hard wall, wall-polymer surface tension, and effective depletion potential are all calculated as a function of concentration and solvent quality. We find important differences between polymers in good and theta solvents. ...

متن کامل

Solvent induced phenomena in a dendronized linear polymer

The properties of a dendronized linear polymer (DP) in dilute solutions depending on solvent quality and temperature are described. The polymer has a contour length of Lc = 1,060 nm. The sample of the fourth generation (PG4) was analyzed in the thermodynamically good solvents dioxane, chloroform, and methanol. The wormlike macromolecule has a persistence length lp = 7 nm in dioxane and a cross-...

متن کامل

A Brownian Dynamics Study of Crossover Scaling in Semidilute Polymer Solutions

Understanding the dynamics of polymer solutions in the semidilute regime is important not only from the point of view of advancing fundamental knowledge in polymer science but also from the point of view of technological applications. The behavior of semidilute polymer solutions varies significantly with concentration and solvent quality, which are reflected in the concentration driven crossove...

متن کامل

Virial coefficients and osmotic pressure in polymer solutions in good-solvent conditions.

We determine the second, third, and fourth virial coefficients appearing in the density expansion of the osmotic pressure Pi of a monodisperse polymer solution in good-solvent conditions. Using the expected large-concentration behavior, we extrapolate the low-density expansion outside the dilute regime, obtaining the osmotic pressure for any concentration in the semidilute region. Comparison wi...

متن کامل

Theory of semi-dilute polymer solutions

2014 Some properties of semi-dilute poor and good solvent polymer solutions are examined within the framework of the field-theoretic formulism. The uncontrollable polydispersivity inherent in the field-theoretic formulism is shown to produce no errors if the quantity under investigation is molecular weight independent. A renormalization group cross-over calculation correct to order 03B5 is perf...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • The Journal of chemical physics

دوره 125 9  شماره 

صفحات  -

تاریخ انتشار 2006